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Oxidative dehydrogenation of propane over Fe-BEA catalysts

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F08%3A00315405" target="_blank" >RIV/61388955:_____/08:00315405 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Oxidative dehydrogenation of propane over Fe-BEA catalysts

  • Original language description

    Catalytic oxidative dehydrogenation of propane (ODHP) by N2O over Fe-BEA catalysts has been studied in continuous feed regime against time and with periodic changing of in-let feed composition under reaction-regeneration cycles. The influence of processparameters on the propylene production has been evaluated, namely N2O/propane ratio and crystal size of the parent zeolite. The particle size (micro- vs. nano-particles) of the catalyst has been shown to be a crucial parameter for propylene yield and catalyst selectivity it higher temperatures. The nano-sized catalyst exhibits superior propylene formation in comparison with micro-sezed one. Time dependent performance of ODHP was carried out using reactant streams containing N2O or N2O with O2. eactivation of the catalysts by oxidation pulses revealed that short pulses of oxygen are sufficient to regenerate the active sites and stabilize propylene yield.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F06%2F1254" target="_blank" >GA104/06/1254: From dynamic analysis towards dynamic control of catalytic reaction on zeolites</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Zeolites and Related Materials: Trends, Targets and Challenges

  • ISBN

    978-0-444-53297-8

  • ISSN

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

  • Publisher name

    Elsevier B.V./Ltd

  • Place of publication

    Oxford

  • Event location

    Paris

  • Event date

    Sep 1, 2008

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article