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Aluminum Siting in the Framework of Silicon Rich Zeolites. A ZSM-5 study

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F08%3A00315569" target="_blank" >RIV/61388955:_____/08:00315569 - isvavai.cz</a>

  • Alternative codes found

    RIV/61389013:_____/08:00315569

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Aluminum Siting in the Framework of Silicon Rich Zeolites. A ZSM-5 study

  • Original language description

    27Al 3Q MAS NMR spectroscopy and DFT/MM calculations were employed to study the Al siting in eleven differently synthesized samples of the ZSM-5 zeolite. The results of our study reveal that the occupation of the distinguishable framework T sites by Al and the concentration of Al in these T sites are neither random nor controlled by a simple rule. They both depend on the conditions of the zeolite synthesis. We further found that at least 10 out of the 24 distinguishable framework T sites are occupied byAl in our ZSM-5 samples.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F06%2F1449" target="_blank" >GA203/06/1449: Quantum chemistry modeling of structure, properties and catalytic activity of zeolites employing embedding approaches</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Zeolites and Related Materials: Trends, Targets and Challenges

  • ISBN

    978-0-444-53297-8

  • ISSN

  • e-ISSN

  • Number of pages

    6

  • Pages from-to

  • Publisher name

    Elsevier B.V./Ltd

  • Place of publication

    Oxford

  • Event location

    Paris

  • Event date

    Sep 1, 2008

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article