An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands

Result code in IS VaVaI

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Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands

Original language description

The paramagnetic compound [Ru(NO)(Q)(terpy)](PF6)2 (Q = 4,6-Di-tert.-butyl-N-phenyl-o-iminobenzoquinone) was prepared via the intermediates [RuCl(Q)(terpy)](ClO4) and [Ru(NO2)(Q)(terpy)](ClO4). The more stable positional isomer with NO trans to the O donor atom of Q was isolated and characterized. In conjunction with the X-ray crystal structure, IR and EPR studies suggest [RuII(NO+)(Q-)(terpy)]2+ as the most valid oxidation state formulation. DFT calculations confirm oxidation state assignment.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Angewandte Chemie. International Edition in English

ISSN

1433-7851

e-ISSN

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Volume of the periodical

48

Issue of the periodical within the volume

23

Country of publishing house

DE - GERMANY

Number of pages

4

Pages from-to

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UT code for WoS article

000266527800036

EID of the result in the Scopus database

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