All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Proton Pump for O-2 Reduction Catalyzed by 5,10,15,20-Tetraphenylporphyrinatocobalt(II)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F09%3A00329362" target="_blank" >RIV/61388955:_____/09:00329362 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388955:_____/09:00358958

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Proton Pump for O-2 Reduction Catalyzed by 5,10,15,20-Tetraphenylporphyrinatocobalt(II)

  • Original language description

    The role of 5,10,15,20-tetra-phenylporphyrinatocobalt(II) ([Co-(tpp)]) as a catalyst on molecular oxygen (O-2) reduction by ferrocene (Fc) and its two derivatives, methylferrocene (DFc) and decamethylferroccric (DMFc) at a polarized waterl 1,2-dichloroethane (DCE) interface has been studied. The water vertical bar DCE interface essentially acts as a proton pump controlled by the Galvani poten tial difference across the interface. driving the proton transfer from water to DCE. [Co(tpp)] catalyzed O-2 reduction by Fc, DFc and DMFc is then followed to produce hydrogen peroxide (H2O2). The catalytic mechanism is similar to that proposed by Fukuzumi et al. for bulk reactions. This interfacial system provides it platform for a very efficient collection of 11,0, by extraction immediately after its formation in DCE to the adjacent water phase, thus decreasing the possibility of degradation and further reaction with ferrocene derivatives.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemistry - A European Journal

  • ISSN

    0947-6539

  • e-ISSN

  • Volume of the periodical

    15

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000264029500015

  • EID of the result in the Scopus database