Proton transfer across a liquid/liquid interface facilitated by phospholipid interfacial films

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F09%3A00341183" target="_blank" >RIV/61388955:_____/09:00341183 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Proton transfer across a liquid/liquid interface facilitated by phospholipid interfacial films

Original language description

The five-step mechanism proposed earlier for the formation of phospholipid films at aqueous/organic interfaces and for their behaviour involving transfer of protons from the aqueous to the organic phase was further studied by cyclic voltammetry. A theoretical model was created for this mechanism and compared with the experimental results. Both the experimental and theoretical results support the proposed mechanism and evaluate the importance of the individual steps. It seems that the decisive step is the regeneration of the zwitterionic form of the phospholipid at the interface, ensuring stability of the film in time and its continuous functioning. In view of the complexity of the system, a wider selection of methods will be needed for a further studyof this system; the theoretical model will then gradually be made more sophisticated.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/LC06063" target="_blank" >LC06063: Flurescence microscopy in biological and medical research</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Electroanalytical Chemistry

ISSN

1572-6657

e-ISSN

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Volume of the periodical

632

Issue of the periodical within the volume

1-2

Country of publishing house

CH - SWITZERLAND

Number of pages

6

Pages from-to

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UT code for WoS article

000267432300002

EID of the result in the Scopus database

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