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Laser Ablation of FOX-7: Proposed Mechanism of Decomposition

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00358301" target="_blank" >RIV/61388955:_____/11:00358301 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1021/ac1028769" target="_blank" >http://dx.doi.org/10.1021/ac1028769</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/ac1028769" target="_blank" >10.1021/ac1028769</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Laser Ablation of FOX-7: Proposed Mechanism of Decomposition

  • Original language description

    A novel high-energy explosive material, FOX-7 (1,1-diamino-2, 2-dinitroethylene), was studied using a combination of laser-induced breakdown spectroscopy (LIBS) and selected ion flow tube mass spectrometry (SIFT-MS). The LIBS technique uses short laser pulses (an ArF excimer laser) as the energy source to convert small quantities of a sample into plasma and to induce the emission of its molecular fragments or atoms. SIFT-MS is a novel method for absolute quantification based on chemical ionization usingthree reagent ions, with the ability to determine concentrations of trace gases and vapors of volatile organic compounds in real time. SIFT-MS was used to study the release of NO, NO2, HCN, HONO, HCHO, CH3CH2OH, and C2H2 after laser ablation of the explosive compound FOX-7 in solid crystalline form. The radiation emitted after excitation was analyzed using a time resolved UV-vis spectrometer with an ICCD detector.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Analytical Chemistry

  • ISSN

    0003-2700

  • e-ISSN

  • Volume of the periodical

    83

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    1069-1077

  • UT code for WoS article

    000286689600062

  • EID of the result in the Scopus database