Laser Ablation of FOX-7: Proposed Mechanism of Decomposition
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00358301" target="_blank" >RIV/61388955:_____/11:00358301 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ac1028769" target="_blank" >http://dx.doi.org/10.1021/ac1028769</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ac1028769" target="_blank" >10.1021/ac1028769</a>
Alternative languages
Result language
angličtina
Original language name
Laser Ablation of FOX-7: Proposed Mechanism of Decomposition
Original language description
A novel high-energy explosive material, FOX-7 (1,1-diamino-2, 2-dinitroethylene), was studied using a combination of laser-induced breakdown spectroscopy (LIBS) and selected ion flow tube mass spectrometry (SIFT-MS). The LIBS technique uses short laser pulses (an ArF excimer laser) as the energy source to convert small quantities of a sample into plasma and to induce the emission of its molecular fragments or atoms. SIFT-MS is a novel method for absolute quantification based on chemical ionization usingthree reagent ions, with the ability to determine concentrations of trace gases and vapors of volatile organic compounds in real time. SIFT-MS was used to study the release of NO, NO2, HCN, HONO, HCHO, CH3CH2OH, and C2H2 after laser ablation of the explosive compound FOX-7 in solid crystalline form. The radiation emitted after excitation was analyzed using a time resolved UV-vis spectrometer with an ICCD detector.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Analytical Chemistry
ISSN
0003-2700
e-ISSN
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Volume of the periodical
83
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
1069-1077
UT code for WoS article
000286689600062
EID of the result in the Scopus database
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