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Acidic and catalytic properties of hierarchical zeolites and hybrid ordered mesoporous materials assembled from MFI protozeolitic units

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00359005" target="_blank" >RIV/61388955:_____/11:00359005 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jcat.2011.02.007" target="_blank" >http://dx.doi.org/10.1016/j.jcat.2011.02.007</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jcat.2011.02.007" target="_blank" >10.1016/j.jcat.2011.02.007</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Acidic and catalytic properties of hierarchical zeolites and hybrid ordered mesoporous materials assembled from MFI protozeolitic units

  • Original language description

    Two types of MFI zeolitic materials with improved accessibility, hierarchical zeolites and hybrid ordered mesoporous materials are here compared in terms of textural, acidic and catalytic properties. In both cases, protozeolitic units were employed as starting building blocks, the growth of which was perturbed by a silanization agent (hierarchical ZSM-5) or controlled by assembling around surfactant micelles (hybrid ordered mesoporous material, HZM). Likewise, two standard samples (nanocrystalline ZSM-5and Al-MCM-41) were used as reference. Nitrogen adsorption measurements confirmed the presence of a secondary porosity and a high share of non-microporous surface area in hierarchical ZSM-5, whereas no significant amount of micropores was detected in the hybrid HZM sample. However, 27Al MAS NMR measurements indicated that zeolitic fragments are present within the walls of the latter sample.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Catalysis

  • ISSN

    0021-9517

  • e-ISSN

  • Volume of the periodical

    279

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    15

  • Pages from-to

    366-380

  • UT code for WoS article

    000289919800015

  • EID of the result in the Scopus database