Ionic partition diagram of tetraphenylporphyrin at the water|1,2-dichloroethane interface

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00359544" target="_blank" >RIV/61388955:_____/11:00359544 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jelechem.2010.12.001" target="_blank" >http://dx.doi.org/10.1016/j.jelechem.2010.12.001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jelechem.2010.12.001" target="_blank" >10.1016/j.jelechem.2010.12.001</a>

Result language
angličtina
Original language name
Ionic partition diagram of tetraphenylporphyrin at the water|1,2-dichloroethane interface
Original language description
From the thermodynamic data obtained by ion-transfer voltammetry, we derive here the ionic partition diagram of 5,10,15,20-tetraphenyl-21H,23H-porphine (H2TPP) at the water|1,2-dichloroethane interface using a simple Born solvation model. This zone diagram shows under which form this porphyrin is present, i.e. neutral, monoprotonated or diprotonated, and in which phase i.e. either in the aqueous or the organic phase as a function of the aqueous pH and the interface polarisation that can be controlled externally or by the distribution of supporting electrolytes. This diagram explains why the monoprotonated form has been difficult to observe when doing biphasic pH titrations.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
—

Project
<a href="/en/project/OC%20177" target="_blank" >OC 177: Molecular catalysis at liquid-liquid interfaces: towards chemical fuel cells</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)