Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00361464" target="_blank" >RIV/61388955:_____/11:00361464 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om100969q" target="_blank" >http://dx.doi.org/10.1021/om100969q</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om100969q" target="_blank" >10.1021/om100969q</a>
Alternative languages
Result language
angličtina
Original language name
Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand
Original language description
Using the noninnocent ligand Q[= 4,6-di-tert-butyl-(2-methylthiophenylimino)-o-berizoquinone] with a thioether group as potential coordination function, it has been possible to substantiate a single-electron transfer induced oxidative addition;within thecomplex [IrCp*Q](0/+) (Cp* = C(5)Me(5)) via structural characterization (catecholato -> semiquinonato transition coupled with reversible S -> Ir coordination), via cyclic voltammetry, EPR, and DFT (semiquinone formulation with about 8% Ir participation). The intramolecular rearrangement of the 16-electron precursor [IrCp*Q] triggered by electron removal illuminates the complementary activities of the substrate binding metal and the electron-buffering ligand as was recently employed by Ringenberg et al.in dihydrogen activation (Organometallics 2010, 29, 1956).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
30
Issue of the periodical within the volume
6
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
1414-1418
UT code for WoS article
000288470900024
EID of the result in the Scopus database
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