Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00361650" target="_blank" >RIV/61388955:_____/11:00361650 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/zaac.201100026" target="_blank" >http://dx.doi.org/10.1002/zaac.201100026</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/zaac.201100026" target="_blank" >10.1002/zaac.201100026</a>
Alternative languages
Result language
angličtina
Original language name
Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation
Original language description
The copper(I) complexes [Cu(L(4))](ClO(4)), L(4) = 1,6-bis(N-methyl-1H-benzimidazol-2-yl)-2,5-dithiahexane (bmbdh) or 1,7-bis(N-methyl-1H-benzimidazol-2-yl)-2,6-dithiaheptane (bmdhp) were obtained and investigated through structure analysis (bmdhp compounds), cyclic voltammetry, UV/Vis/NIR and EPR spectroelectrochemistry. Structure comparison of the complexes [Cu(bmdhp)](ClO(4)) (1) and [Cu(bmdhp)](SO(3)CF(3)) (2) with the previously reported [Cu(I)(bdhp)(H(2)O)](PF(6))(0.66)(BF(4))(0.34) (4), bdhp = 1,7-bis(1H-benzimidazol-2-yl)-2,6-dithiaheptane, with the related [Cu(I)(mmb)(2)](BF(4)) (5), mmb = 1-methyl-2-methylthiomethyl-1H-benzimidazole, with the oxidised [Cu(II)(bmdhp)(H(2)O)](ClO(4))(2) (7), and with the zinc(II) species [Zn(bmbdh)(H(2)O)(SO(3)CF(3))](SO(3)CF(3)) (8) and {[Zn(mu-bmdhp)(H(2)O)(SO(3)CF(3))](2)}(SO(3)CF(3)) (9) reveal a variety of coordination numbers, L(4) ligand coordination modes, M-N bond lengths and especially N-M-N angles...
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F09%2F0705" target="_blank" >GA203/09/0705: Transfer of charge in single and assembled molecules</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für anorganische und allgemeine Chemie
ISSN
0044-2313
e-ISSN
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Volume of the periodical
637
Issue of the periodical within the volume
7
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
930-934
UT code for WoS article
000292334400020
EID of the result in the Scopus database
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