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Graphene Nanoplatelet Cathode for Co(III)/(II) Mediated Dye-Sensitized Solar Cells

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00367630" target="_blank" >RIV/61388955:_____/11:00367630 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1021/nn203416d" target="_blank" >http://dx.doi.org/10.1021/nn203416d</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/nn203416d" target="_blank" >10.1021/nn203416d</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Graphene Nanoplatelet Cathode for Co(III)/(II) Mediated Dye-Sensitized Solar Cells

  • Original language description

    Graphene nanoplatelets (GNP) in the form of thin semitransparent film on F-doped SnO2 (FTO) exhibit high electrocatalytic activity for Co(L)2; where L is 6-(1H-pyrazol-1-yl)-2,2-bipyridine. The exchange current densities for the Co2+/3+(L)2 redox reaction scaled linearly with the GNP film?s optical absorbance, and they were by 1?2 orders of magnitude larger than those for the I3?/I? couple on the same electrode. The electrocatalytic activity of GNP films with optical transmission below 88% is outperforming the activity of platinized FTO for the Co2+/3+(L)2 redox reaction. Dye-sensitized solar cells with Y123 dye adsorbed on TiO2 photoanode achieved energy conversion efficiencies between 8 and 10% for both GNP and Pt-based cathodes. However, the cell with GNP cathode is superior to that with Pt-FTO cathode particularly in fill factors and in the efficiency at higher illumination intensities.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS NANO

  • ISSN

    1936-0851

  • e-ISSN

  • Volume of the periodical

    5

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    9171-9178

  • UT code for WoS article

    000297143300079

  • EID of the result in the Scopus database