Thermodynamic aspects of the electron transfer across the interface between water and a hydrophobic redox-active ionic liquid

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00367631" target="_blank" >RIV/61388955:_____/11:00367631 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.electacta.2011.10.003" target="_blank" >http://dx.doi.org/10.1016/j.electacta.2011.10.003</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.electacta.2011.10.003" target="_blank" >10.1016/j.electacta.2011.10.003</a>

Result language

angličtina

Original language name

Thermodynamic aspects of the electron transfer across the interface between water and a hydrophobic redox-active ionic liquid

Original language description

Ion and electron transfer reactions at the interface between a redox-active ionic liquid (IL), (ferrocenylmethyl)dodecyldimethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (FcMDDATFPB), and water were investigated by cyclic voltammetry (CV) using the FcMDDATFPB membrane cell. The redox-active IL was shown to exhibit the same ion selectivity as the structurally similar but redox-inactive tridodecylmethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Ion transfer potentials evaluatedfrom CV measurements allowed establishing the scale of absolute potential differences for the interfacial oxidation of FcMDDA+ with the aqueous redox species including IrCl62, Fe(CN)63, Mo(CN)83, ICl2 or IBr2. In order to rationalize experimental data,the theory of CV was developed for an electron transfer at one membrane interface that is coupled with the ion transfer at the other membrane interface.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Electrochimica acta

ISSN

0013-4686

e-ISSN

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Volume of the periodical

58

Issue of the periodical within the volume

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Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

606-613

UT code for WoS article

000298765300083

EID of the result in the Scopus database

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