High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00375913" target="_blank" >RIV/61388955:_____/12:00375913 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.cattod.2011.08.001" target="_blank" >http://dx.doi.org/10.1016/j.cattod.2011.08.001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cattod.2011.08.001" target="_blank" >10.1016/j.cattod.2011.08.001</a>
Alternative languages
Result language
angličtina
Original language name
High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride
Original language description
Catalytic behavior of metal-organic-frameworks (MOFs) Cu-3(BTC)(2), MIL-100(Fe) and MIL-100(Cr) was investigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY. It has been clearly shown that MIL-100(Fe) exhibit much higher conversion of benzoyl chloride with excellent selectivity in p-xylene acylation. The performance of MIL-100(Fe) catalyst was favorable with those of other conventional heterogeneous catalysts like zeolites. Conversion ofbenzoyl chloride equal to 100% was achieved over MIL-100(Fe) with 20-30 min under optimized reaction conditions. It is assumed that unsaturated Lewis acid sites associated with the presence of Fe exhibit optimum acid strength for catalyzing this acylation reaction.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA104%2F07%2F0383" target="_blank" >GA104/07/0383: Development of new heterogeneous catalysts for acylation reactions</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Catalysis Today
ISSN
0920-5861
e-ISSN
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Volume of the periodical
179
Issue of the periodical within the volume
1
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
85-90
UT code for WoS article
000298404600011
EID of the result in the Scopus database
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