Competitive inhibition of a metal-free porphyrin oxygen-reduction catalyst by water
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00376110" target="_blank" >RIV/61388955:_____/12:00376110 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/C2CC31082A" target="_blank" >http://dx.doi.org/10.1039/C2CC31082A</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C2CC31082A" target="_blank" >10.1039/C2CC31082A</a>
Alternative languages
Result language
angličtina
Original language name
Competitive inhibition of a metal-free porphyrin oxygen-reduction catalyst by water
Original language description
A stopped-flow method is used to study the effects of water and reactant acid anion TB = tetrakis(pentafluorophenyl)borate on the homogeneous oxygen reduction catalyzed by the protonated tetraphenylporphyrin. Observed competitive inhibition of the catalyst is linked to the DFT free energy of extraction of O2, water, and TB from the porphyrin complex.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP208%2F11%2F0697" target="_blank" >GAP208/11/0697: Catalysis of the oxygen reduction by metal-free porphyrins at the electrochemically polarized liquid-liquid interfaces</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Communications
ISSN
1359-7345
e-ISSN
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Volume of the periodical
48
Issue of the periodical within the volume
34
Country of publishing house
GB - UNITED KINGDOM
Number of pages
3
Pages from-to
4094-4096
UT code for WoS article
000302017000018
EID of the result in the Scopus database
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