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Adsorption of Carbon Dioxide on Sodium and Potassium Forms of STI?Zeolite

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00379329" target="_blank" >RIV/61388955:_____/12:00379329 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1002/cplu.201200089" target="_blank" >http://dx.doi.org/10.1002/cplu.201200089</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/cplu.201200089" target="_blank" >10.1002/cplu.201200089</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Adsorption of Carbon Dioxide on Sodium and Potassium Forms of STI?Zeolite

  • Original language description

    Sodium and potassium forms of STI?zeolite synthesized with Si/Al ratios 15, 25, and 35 were characterized using X-ray powder diffraction and nitrogen adsorption at 77?K. To obtain detailed information on the effect of alkali metal cations on CO2 adsorption, the temperature dependence of CO2 isotherms was investigated in the temperature range from 273 to 333?K. Based on these data, isosteric heats of adsorption of CO2 were determined. It was found that the isosteric heat of CO2 adsorption attains the highest values on the sodium form of STI?zeolite with a Si/Al ratio of 15. The lowest values were found with both sodium and potassium forms of STI?zeolite having a Si/Al ratio of 35. Heats of adsorption of CO2 obtained for STI?zeolites were discussed in detail and compared with those of FER, MFI, MEL, TUN, and IMF structural types. This comparison revealed that isosteric heats of adsorption of CO2 on STI?zeolites are lower by approximately 8?kJ?mol1 compared with heats of adsorption for FE

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F08%2F0604" target="_blank" >GA203/08/0604: Advanced molecular sieves for capture and storage of CO2 and H2</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ChemPlusChem

  • ISSN

    2192-6506

  • e-ISSN

  • Volume of the periodical

    77

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    675-681

  • UT code for WoS article

    000307401800008

  • EID of the result in the Scopus database