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Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2-with Coordinating Thioether Appendix

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00379899" target="_blank" >RIV/61388955:_____/12:00379899 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1002/ejic.201200225" target="_blank" >http://dx.doi.org/10.1002/ejic.201200225</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/ejic.201200225" target="_blank" >10.1002/ejic.201200225</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2-with Coordinating Thioether Appendix

  • Original language description

    Complexes [M(LN,O,S)2] [M = Ru, Os; (LN,O,S)2 = 4,6-di-tert-butyl(2-methylthiophenylamido)-o-phenolate] were obtained and structurally characterized as metal(IV) complexes with mer-configured tridentate ligands. Two reversible oxidations and one (Os) ortwo (Ru) reversible reductions were investigated by EPR and UV/Vis/NIR spectroelectrochemistry. The first reduction leads to EPR-silent MIII species, whereas the oxidation produces iminosemiquinone complexes with ligand-centered spin and small-metal participation at the singly occupied MO. Absorptions in the visible and near-IR region are assigned with the help of time-dependent (TD)-DFT calculations.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LD11086" target="_blank" >LD11086: Quantum chemical interpretation and prediction of spectral characteristics of heavy transition metal complexes</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    European Journal of Inorganic Chemistry

  • ISSN

    1434-1948

  • e-ISSN

  • Volume of the periodical

    2012

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    8

  • Pages from-to

    3569-3576

  • UT code for WoS article

    000306733800008

  • EID of the result in the Scopus database