Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2-with Coordinating Thioether Appendix
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00379899" target="_blank" >RIV/61388955:_____/12:00379899 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201200225" target="_blank" >http://dx.doi.org/10.1002/ejic.201200225</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201200225" target="_blank" >10.1002/ejic.201200225</a>
Alternative languages
Result language
angličtina
Original language name
Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2-with Coordinating Thioether Appendix
Original language description
Complexes [M(LN,O,S)2] [M = Ru, Os; (LN,O,S)2 = 4,6-di-tert-butyl(2-methylthiophenylamido)-o-phenolate] were obtained and structurally characterized as metal(IV) complexes with mer-configured tridentate ligands. Two reversible oxidations and one (Os) ortwo (Ru) reversible reductions were investigated by EPR and UV/Vis/NIR spectroelectrochemistry. The first reduction leads to EPR-silent MIII species, whereas the oxidation produces iminosemiquinone complexes with ligand-centered spin and small-metal participation at the singly occupied MO. Absorptions in the visible and near-IR region are assigned with the help of time-dependent (TD)-DFT calculations.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LD11086" target="_blank" >LD11086: Quantum chemical interpretation and prediction of spectral characteristics of heavy transition metal complexes</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
2012
Issue of the periodical within the volume
11
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
3569-3576
UT code for WoS article
000306733800008
EID of the result in the Scopus database
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