Reaction of Phthalaldehyde with Aminoethanol under Different Conditions: Products and Mechanisms of Their Formation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00385299" target="_blank" >RIV/61388955:_____/12:00385299 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/jhet.1121" target="_blank" >http://dx.doi.org/10.1002/jhet.1121</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/jhet.1121" target="_blank" >10.1002/jhet.1121</a>
Alternative languages
Result language
angličtina
Original language name
Reaction of Phthalaldehyde with Aminoethanol under Different Conditions: Products and Mechanisms of Their Formation
Original language description
Analysis of amino acids and very efficient disinfection procedures are based on the reaction of phthalaldehyde (OPA) with primary amines. In this contribution, aminoethanol (=kolamin) as a nitrogen-containing nucleophile was used for the investigation ofits reaction mechanism with OPA performed in basic aqueous buffered media (pH 9.5), where an influence of hydration or solvation is expected, and in anhydrous acetonitrile. Depending on the detailed reaction conditions, seven products were isolated andtheir structures determined by NMR, mass spectrometry, and X-ray structure analysis. Reaction mechanisms are proposed, which involve hydride transfers to OPA (Cannizzaro-type reaction).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/ME09002" target="_blank" >ME09002: Chemical and Electrochemical Properties of Aromatic Dialdehydes and their Derivatives, Chemical Principles of Sensors for Aminoacids and New Disinfection Processes</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Heterocyclic Chemistry
ISSN
0022-152X
e-ISSN
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Volume of the periodical
49
Issue of the periodical within the volume
5
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
1202-1209
UT code for WoS article
000310562600034
EID of the result in the Scopus database
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