The effect of substrate size in the Beckmann rearrangement: MOFs vs. zeolites
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00389149" target="_blank" >RIV/61388955:_____/13:00389149 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.cattod.2012.09.008" target="_blank" >http://dx.doi.org/10.1016/j.cattod.2012.09.008</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cattod.2012.09.008" target="_blank" >10.1016/j.cattod.2012.09.008</a>
Alternative languages
Result language
angličtina
Original language name
The effect of substrate size in the Beckmann rearrangement: MOFs vs. zeolites
Original language description
Catalytic activity of CuBTC and FeBTC was investigated in Beckmann rearrangement of a series of aromatic and non-aromatic oximes and compared with that of zeolites Beta and USY. The reactivity of substrates in Beckmann rearrangement increases in the order camphor oxime < cyclohexanone oxime < indanone oxime < acetophenone oxime. While zeolites show higher activity in the transformation of relatively small aromatic (acetophenone oxime, indanone oxime) and non-aromatic oximes (cyclohexanone oxime) providing 100% selectivity to the target lactams in all reactions, CuBTC was the most active in transformation of bulky oximes. It was deduced, that textural preferences of CuBTC may be the reason of its capability to facilitate the transformation of bulky camphor oxime in comparison with zeolites Beta and USY.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Catalysis Today
ISSN
0920-5861
e-ISSN
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Volume of the periodical
204
Issue of the periodical within the volume
APR 2013
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
94-100
UT code for WoS article
000314825900014
EID of the result in the Scopus database
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