Supramolecular interactions between chiral ions: Synthesis and characterization of [M-II(bpy)(3)][VO(O-2)(ox)(bpy)].7H(2)O (M = Fe and Ni)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00391989" target="_blank" >RIV/61388955:_____/13:00391989 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2012.10.019" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2012.10.019</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2012.10.019" target="_blank" >10.1016/j.molstruc.2012.10.019</a>

Result language
angličtina
Original language name
Supramolecular interactions between chiral ions: Synthesis and characterization of [M-II(bpy)(3)][VO(O-2)(ox)(bpy)].7H(2)O (M = Fe and Ni)
Original language description
Two new compounds containing chiral cations and anions, [M(bpy)(3)][VO(O-2)(ox)(bpy)](2)center dot 7H(2)O (M = Fe, Ni; bpy = 2,2'-bipyridine; ox = oxalato(2-)) have been prepared and characterized by elemental analysis, vibrational spectra in the solid state, and by V-51 NMR and electronic spectroscopy in solution. The compounds are isostructural and racemic. The crystal structure contains two kinds of alternating (homochiral) triple layers: (i) the layer formed by Delta-[M(bpy)(3)](2+) cations intercalated between two layers of A-[VO(O-2)(ox)(bpy)](-), and (ii) the layer formed by Lambda-[M(bpy)(3)](2+) cations intercalated between two layers of B-[VO(O-2)(ox)(bpy)](-) (A- and B-denote different enantiomers of anions).
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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