Oxidation of cycloalkanes with molecular oxygen in the presence of salen metallocomplexes in thermomorphic conditions

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00393167" target="_blank" >RIV/61388955:_____/13:00393167 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.catcom.2013.04.026" target="_blank" >http://dx.doi.org/10.1016/j.catcom.2013.04.026</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.catcom.2013.04.026" target="_blank" >10.1016/j.catcom.2013.04.026</a>

Result language

angličtina

Original language name

Oxidation of cycloalkanes with molecular oxygen in the presence of salen metallocomplexes in thermomorphic conditions

Original language description

The oxidation of cycloalkanes with molecular oxygen, catalyzed by two groups of metallosalen complexes, was studied. The first group consisted of salen complexes with different metals such as Mn, Fe, Co, Ni, Cu, Zn, while the second group was composed ofmanganese salen complexes with different substituents (t-butyl electron-donating substituents and/or electron-withdrawing perfluoroalkyl substituents). Mn, Fe and Co salen complexes are the most active catalysts, while Ni, Cu and Zn salen complexes arefar less efficient. The introduction of t-butyl electron-donating substituents into Mnsalen complex increases the catalytic activity and catalysts solubility in the reaction mixture. The introduction of perfluoroalkyl electron-withdrawing substituents enhances the catalytic activity and renders the solubility of the catalyst temperature dependent (thermomorphic behaviour), thus allowing one to recover them easily after the reaction by simply cooling the system to room temperature. The sy

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Catalysis Communication

ISSN

1566-7367

e-ISSN

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Volume of the periodical

39

Issue of the periodical within the volume

SEP 2013

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

4

Pages from-to

102-105

UT code for WoS article

000321604300022

EID of the result in the Scopus database

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