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Enhancement of Activity and Selectivity in Acid-Catalyzed Reactions by Dealuminated Hierarchical Zeolites

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00420720" target="_blank" >RIV/61388955:_____/13:00420720 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388980:_____/13:00420720

  • Result on the web

    <a href="http://dx.doi.org/10.1002/anie.201206557" target="_blank" >http://dx.doi.org/10.1002/anie.201206557</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/anie.201206557" target="_blank" >10.1002/anie.201206557</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Enhancement of Activity and Selectivity in Acid-Catalyzed Reactions by Dealuminated Hierarchical Zeolites

  • Original language description

    High-silica zeolites with crystalline aluminosilicate frame- works balance the charge of strongly acidic protons during the processing of oil, in petrochemistry, and increasingly in numerous organic syntheses. The transformation of hydro- carbons is controlled by the concentration and strength of the acid sites and the dimensions and architecture of the inner pores. Zeolite micropores, which have a diameter similar to organic molecules, govern the shape selectivity of the reaction in the inner space, but also result in slow transport of reactants and products, thus limiting the reaction rate. [1] Several approaches have been developed to enhance the mass transport by using zeolite nanosheets and nanocrystals, [2?4] or zeolites that contain both micro-and mesopores. The latter hierarchical zeolites were prepared by confined crystal growth, [5,6] by using polymers as mesoporogens, [7] or through post-synthesis desilication or dealumination processes.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Angewandte Chemie. International Edition in English

  • ISSN

    1433-7851

  • e-ISSN

  • Volume of the periodical

    52

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    4

  • Pages from-to

    2038-2041

  • UT code for WoS article

    000314654000028

  • EID of the result in the Scopus database