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Capacitive contribution to Li-storage in TiO2 (B) and TiO2 (anatase)

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00395692" target="_blank" >RIV/61388955:_____/14:00395692 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/14:10159366

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jpowsour.2013.07.073" target="_blank" >http://dx.doi.org/10.1016/j.jpowsour.2013.07.073</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jpowsour.2013.07.073" target="_blank" >10.1016/j.jpowsour.2013.07.073</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Capacitive contribution to Li-storage in TiO2 (B) and TiO2 (anatase)

  • Original language description

    Analysis of cyclic voltammograms of Li insertion into TiO2 (B) and anatase provides information about capacitive contributions to overall charge of Li-storage. The enhancement of 30% is found in capacitive contributions (normalized to the total stored charges) in TiO2 (B) compared to that in anatase, in spite of ca. three times smaller surface area of the former. Different charging mechanism explains facilitated Li? insertion in TiO2 (B). The difference is caused mainly by pseudocapacitive Li-storage inthe bulk TiO2 (B). Deconvolution of cyclic voltammograms also indicates different capacitive contributions of the two voltammetric peaks, S1 and S2 of TiO2 (B). These results provide novel insight into the Li-storage in TiO2 (B) and its difference fromthat in anatase.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Power Sources

  • ISSN

    0378-7753

  • e-ISSN

  • Volume of the periodical

    246

  • Issue of the periodical within the volume

    JAN 2014

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    7

  • Pages from-to

    103-109

  • UT code for WoS article

    000326661100015

  • EID of the result in the Scopus database