Oxidation and reduction response of a-diimine complexes with tricarbonylrhenium halides and pseudohalides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00428319" target="_blank" >RIV/61388955:_____/14:00428319 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.08.030" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2013.08.030</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.08.030" target="_blank" >10.1016/j.jorganchem.2013.08.030</a>
Alternative languages
Result language
angličtina
Original language name
Oxidation and reduction response of a-diimine complexes with tricarbonylrhenium halides and pseudohalides
Original language description
Compounds [Re(CO)(3)X(R-DAB)], X = Cl, Br, CN, NCS and R-DAB = RN=CH-CH=NR (R = tert-butyl) were obtained, structurally characterized, and studied with regard to their oxidation and reduction behavior using cyclic voltammetry, EPR, IR and UV-vis-NIR spectroelectrochemistry. Whereas the halide compounds exhibit more reversible oxidation processes, the pseudohalide complexes display reversible one-electron reduction but irreversible oxidation. DFT and TD-DFT calculations were employed to confirm the experimentally derived electronic structures and spectral properties.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LD11086" target="_blank" >LD11086: Quantum chemical interpretation and prediction of spectral characteristics of heavy transition metal complexes</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
751
Issue of the periodical within the volume
SI
Country of publishing house
CH - SWITZERLAND
Number of pages
8
Pages from-to
678-685
UT code for WoS article
000329864700071
EID of the result in the Scopus database
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