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Oxidation and reduction response of a-diimine complexes with tricarbonylrhenium halides and pseudohalides

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00428319" target="_blank" >RIV/61388955:_____/14:00428319 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jorganchem.2013.08.030" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2013.08.030</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jorganchem.2013.08.030" target="_blank" >10.1016/j.jorganchem.2013.08.030</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Oxidation and reduction response of a-diimine complexes with tricarbonylrhenium halides and pseudohalides

  • Original language description

    Compounds [Re(CO)(3)X(R-DAB)], X = Cl, Br, CN, NCS and R-DAB = RN=CH-CH=NR (R = tert-butyl) were obtained, structurally characterized, and studied with regard to their oxidation and reduction behavior using cyclic voltammetry, EPR, IR and UV-vis-NIR spectroelectrochemistry. Whereas the halide compounds exhibit more reversible oxidation processes, the pseudohalide complexes display reversible one-electron reduction but irreversible oxidation. DFT and TD-DFT calculations were employed to confirm the experimentally derived electronic structures and spectral properties.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LD11086" target="_blank" >LD11086: Quantum chemical interpretation and prediction of spectral characteristics of heavy transition metal complexes</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Organometallic Chemistry

  • ISSN

    0022-328X

  • e-ISSN

  • Volume of the periodical

    751

  • Issue of the periodical within the volume

    SI

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    8

  • Pages from-to

    678-685

  • UT code for WoS article

    000329864700071

  • EID of the result in the Scopus database