Experimental and theoretical study of the mechanism of formation of astrochemically important C2n+1N anions via ion/molecule reactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00429032" target="_blank" >RIV/61388955:_____/14:00429032 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ijms.2014.04.008" target="_blank" >http://dx.doi.org/10.1016/j.ijms.2014.04.008</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ijms.2014.04.008" target="_blank" >10.1016/j.ijms.2014.04.008</a>
Alternative languages
Result language
angličtina
Original language name
Experimental and theoretical study of the mechanism of formation of astrochemically important C2n+1N anions via ion/molecule reactions
Original language description
The reactions of C2n+1N anions and their complexes with cyanoacetylene, HC3N, and hydrogen cyanide, HCN, were studied experimentally using methods of tandem mass spectrometry. The experiments showed that bare C2n+1N anions react with HC3N rather slowly by elimination of HCN and formation of C2n+3N anion. On the other hand, when the C2n+1N anions are solvated by one or more HC3N molecules, this reaction becomes significantly more efficient. A mechanism and energetics of this reaction were also studied byab initio methods of quantum chemistry. The reactions described in detail in this communication may represent a possible way of formation of large anions found in the ionosphere of Titan.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP208%2F11%2F0446" target="_blank" >GAP208/11/0446: Experimental and theoretical study of chemical reactions ocuring in the Titan's ionosphere</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
International Journal of Mass Spectrometry
ISSN
1387-3806
e-ISSN
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Volume of the periodical
367
Issue of the periodical within the volume
JUN 2014
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
9
Pages from-to
1-9
UT code for WoS article
000337777100001
EID of the result in the Scopus database
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