Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00434756" target="_blank" >RIV/61388955:_____/14:00434756 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s11243-014-9873-2" target="_blank" >http://dx.doi.org/10.1007/s11243-014-9873-2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s11243-014-9873-2" target="_blank" >10.1007/s11243-014-9873-2</a>
Alternative languages
Result language
angličtina
Original language name
Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations
Original language description
Four new compounds composed of chiral complex cations and anions: ?-[Fe(bpy)3] ?-[Fe(bpy)3][V4O8((2R,3R)-tart)2]12H2O (1), ?-[Fe(bpy)3]2?-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (2), ?-[Ni(bpy)3]?-[Ni(bpy)3][V4O8((2R,3R)-tart)2]12H2O (3) and ?-[Ni(bpy)3]2?-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is "hemiracemic" and 2 and 4 are "fully racemic" compounds.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Transition Metal Chemistry
ISSN
0340-4285
e-ISSN
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Volume of the periodical
39
Issue of the periodical within the volume
8
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
8
Pages from-to
893-900
UT code for WoS article
000343836900007
EID of the result in the Scopus database
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