Beyond the volcano limitations in electrocatalysis - oxygen evolution reaction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00434962" target="_blank" >RIV/61388955:_____/14:00434962 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c4cp00571f" target="_blank" >http://dx.doi.org/10.1039/c4cp00571f</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4cp00571f" target="_blank" >10.1039/c4cp00571f</a>
Alternative languages
Result language
angličtina
Original language name
Beyond the volcano limitations in electrocatalysis - oxygen evolution reaction
Original language description
Oxygen evolution catalysis is restricted by the interdependence of adsorption energies of the reaction intermediates and the surface reactivity. The interdependence reduces the number of degrees of freedom available for catalyst optimization. Here it isdemonstrated that this limitation can be removed by active site modification. This can be achieved on ruthenia by incorporation of Ni or Co into the surface, which activates a proton donor-acceptor functionality on the conventionally inactive bridge surface sites. This enhances the actual measured oxygen evolution activity of the catalyst significantly compared to conventional ruthenia.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/IAA400400906" target="_blank" >IAA400400906: Nanocrystalline oxides for selective anodic electrocatalysi</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physical Chemistry Chemical Physics
ISSN
1463-9076
e-ISSN
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Volume of the periodical
16
Issue of the periodical within the volume
27
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
13682-13688
UT code for WoS article
000338116700016
EID of the result in the Scopus database
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