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Beyond the volcano limitations in electrocatalysis - oxygen evolution reaction

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00434962" target="_blank" >RIV/61388955:_____/14:00434962 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/c4cp00571f" target="_blank" >http://dx.doi.org/10.1039/c4cp00571f</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c4cp00571f" target="_blank" >10.1039/c4cp00571f</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Beyond the volcano limitations in electrocatalysis - oxygen evolution reaction

  • Original language description

    Oxygen evolution catalysis is restricted by the interdependence of adsorption energies of the reaction intermediates and the surface reactivity. The interdependence reduces the number of degrees of freedom available for catalyst optimization. Here it isdemonstrated that this limitation can be removed by active site modification. This can be achieved on ruthenia by incorporation of Ni or Co into the surface, which activates a proton donor-acceptor functionality on the conventionally inactive bridge surface sites. This enhances the actual measured oxygen evolution activity of the catalyst significantly compared to conventional ruthenia.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/IAA400400906" target="_blank" >IAA400400906: Nanocrystalline oxides for selective anodic electrocatalysi</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Chemistry Chemical Physics

  • ISSN

    1463-9076

  • e-ISSN

  • Volume of the periodical

    16

  • Issue of the periodical within the volume

    27

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    13682-13688

  • UT code for WoS article

    000338116700016

  • EID of the result in the Scopus database