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High-resolution adsorption analysis of pillared zeolites IPC-3PI and MCM-36

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00435101" target="_blank" >RIV/61388955:_____/14:00435101 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/c4dt00389f" target="_blank" >http://dx.doi.org/10.1039/c4dt00389f</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c4dt00389f" target="_blank" >10.1039/c4dt00389f</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    High-resolution adsorption analysis of pillared zeolites IPC-3PI and MCM-36

  • Original language description

    The porous structure of pillared zeolites IPC-3PI and MCM-36 and their precursors IPC-3P and MCM-22P, respectively, has been investigated by means of a high-resolution adsorption analysis. The analysis was based on argon adsorption isotherms measured at87 K from the relative pressure of 10(-6). The isotherms were processed by means of the t-plot method, which made it possible to distinguish adsorption in micropores from adsorption in mesopores. The pore size distribution was evaluated from argon isotherms using Non-Local Density Functional Theory. The obtained results have shown that the microporous structure of the MWW layers is preserved in both pillared zeolites. In contrast to precursors IPC-3P and MCM-22P, pillared samples are characterized by the formation of a porous structure belonging to the lower mesopore region. The distribution of mesopores in the zeolite IPC-3PI is broader and is shifted to larger widths in comparison with the zeolite MCM-36.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GP13-17593P" target="_blank" >GP13-17593P: Preparation of Novel Structure-Directing Agents for the Synthesis of Zeolites</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Dalton Transactions

  • ISSN

    1477-9226

  • e-ISSN

  • Volume of the periodical

    43

  • Issue of the periodical within the volume

    27

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    10558-10565

  • UT code for WoS article

    000338117200028

  • EID of the result in the Scopus database