ELECTROCHEMISTRY OF FISCHER AMINOCARBENE COMPLEXES: EFFECTS OF STRUCTURE ON REDOX PROPERTIES, ELECTRON DISTRIBUTION, AND REACTION MECHANISMS
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00437065" target="_blank" >RIV/61388955:_____/14:00437065 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/14:43897436
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
ELECTROCHEMISTRY OF FISCHER AMINOCARBENE COMPLEXES: EFFECTS OF STRUCTURE ON REDOX PROPERTIES, ELECTRON DISTRIBUTION, AND REACTION MECHANISMS
Original language description
Carbene complexes are characterized by the presence of a formal double bond between a central metal atom and a carbene ligand, M= CR2. Generally, these compounds are divided into three groups according to the nature of the metal?carbon bond: nucleophilicSchrock carbenes, where the carbon center has a nucleophilic character, M(? +)=C(? ); and electrophilic Fischer carbenes with the metal?carbon bond polarized in the opposite sense M(? )=C(? +) (the fifteenth annual survey describing their chemistry wasrecently published [1]). The third group includes transition-metal complexes with N-heterocyclic carbene ligands (e.g., the Hoveyda?Grubbs catalyst), in which the multiple character of metal?carbon bond is negligible [2]. This chapter is devoted to carbenes of the Fischer type, that is, to aminocarbene complexes.
Czech name
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Czech description
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Classification
Type
C - Chapter in a specialist book
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Book/collection name
Advances in Organometallic Chemistry and Catalysis
ISBN
978-1-118-51014-8
Number of pages of the result
13
Pages from-to
653-665
Number of pages of the book
736
Publisher name
Wiley
Place of publication
Hoboken
UT code for WoS chapter
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