All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Selective Chlorine Evolution Catalysts Based on Mg-Doped Nanoparticulate Ruthenium Dioxide

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00435253" target="_blank" >RIV/61388955:_____/15:00435253 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1149/2.0541501jes" target="_blank" >http://dx.doi.org/10.1149/2.0541501jes</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1149/2.0541501jes" target="_blank" >10.1149/2.0541501jes</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Selective Chlorine Evolution Catalysts Based on Mg-Doped Nanoparticulate Ruthenium Dioxide

  • Original language description

    Nanocrystalline Mg-doped ruthenium dioxide catalysts with the formula Ru1-xMgxO2 (0 x 20) were synthesized by the spray-freezing freeze-drying technique. Synthesized materials are of nanoparticulate nature and show a single phase diffraction pattern conforming to a tetragonal oxide of the rutile structural type. Magnesium ions are not distributed homogeneously in the material, but exist in Mg-rich clusters as shown by X-ray absorption spectroscopy. The refinement of the Mg EXAFS functions for materialswith low Mg content shows that the magnesium rich clusters contain Mg in a highly strained environment similar to that of the rutile-type structure. The Mg environment shifts to an ilmenite-type inclusion when Mg occupies more than 10% of all cationic positions. All Mg modified materials are active in oxygen evolution and chlorine evolution reactions. Although the Mg containing catalysts show lower overall activities compared with the non-doped ruthenia, they feature enhanced selectivity

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of the Electrochemical Society

  • ISSN

    0013-4651

  • e-ISSN

  • Volume of the periodical

    162

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    "H23"-"H31"

  • UT code for WoS article

    000345979700100

  • EID of the result in the Scopus database

    2-s2.0-84923385631