Tailoring of the structure of Pt/WO3?ZrO2 catalyst for high activity in skeletal isomerization of C5?C6 paraffins under industrially relevant conditions

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00442954" target="_blank" >RIV/61388955:_____/15:00442954 - isvavai.cz</a>

Alternative codes found

RIV/62243136:_____/15:MPO02CL

Result on the web

<a href="http://dx.doi.org/10.1007/s11164-015-1968-7" target="_blank" >http://dx.doi.org/10.1007/s11164-015-1968-7</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11164-015-1968-7" target="_blank" >10.1007/s11164-015-1968-7</a>

Result language

angličtina

Original language name

Tailoring of the structure of Pt/WO3?ZrO2 catalyst for high activity in skeletal isomerization of C5?C6 paraffins under industrially relevant conditions

Original language description

Optimized Pt/WO3?ZrO2 catalysts were evaluated in the isomerization of C5?C6 paraffins. The catalysts were tailored for optimal activity and selectivity using both the model C6 paraffin mixtures and C5?C6 real raw feeds from the industrial production ofhigh quality gasoline. The optimization included a study of the role of the structure of Pt/WO3?ZrO2 undoped and doped with aluminum, with focus on the nuclearity and nature of WO3 species. The heterogeneity of the structure, acid and redox properties were analysed using UV?Vis and Raman, and supplemented by temperature programmed reduction with hydrogen and desorption of ammonia. The results show a maximum achieved increment of R.O.N. = 14, using a mixture of hexane isomers (hexane g.r.) as raw material, which demonstrated the potential of these materials for an environmentally friendly process for the improvement of transportation fuels.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/FR-TI3%2F316" target="_blank" >FR-TI3/316: *Research and development of highly active catalyst based on ZrO2 and its application for izomerization of C5-C6 hydrocarbons</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Research on Chemical Intermediates

ISSN

0922-6168

e-ISSN

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Volume of the periodical

41

Issue of the periodical within the volume

12

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

13

Pages from-to

9425-9437

UT code for WoS article

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EID of the result in the Scopus database

2-s2.0-84924210717