UV-Vis-NIR spectroelectrochemical study of tetrathiorhenate-bridged diruthenium complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00443985" target="_blank" >RIV/61388955:_____/15:00443985 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2014.05.016" target="_blank" >http://dx.doi.org/10.1016/j.poly.2014.05.016</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2014.05.016" target="_blank" >10.1016/j.poly.2014.05.016</a>

Result language
angličtina
Original language name
UV-Vis-NIR spectroelectrochemical study of tetrathiorhenate-bridged diruthenium complexes
Original language description
The new compound (NEt4)[(acac)(2)RuS2ReS2Ru(acac)(2)] was characterized by cyclic voltammetry to reveal reversible reduction and oxidation behavior. While the redox products proved EPR silent, the UV-Vis-NIR spectroelectrochemistry showed shifted charge-transfer absorptions and a typical near-infrared intervalence (Ru-II -> Ru-III) band at lambda(max) = 1725 nm (epsilon = 1800 M-1 cm(-1)) for the one-electron oxidized intermediate. The results are discussed in comparison to those obtained for [(bPY)2RuS2ReS2RIOPYMC13. (C) 2014 Elsevier Ltd. All rights reserved.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Project
<a href="/en/project/LD14129" target="_blank" >LD14129: Structure and dynamics of excited and redox states of photocatalytic complexes</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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