Catalytic behavior of metal-organic frameworks and zeolites: Rationalization and comparative analysis

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00446847" target="_blank" >RIV/61388955:_____/15:00446847 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.cattod.2014.06.040" target="_blank" >http://dx.doi.org/10.1016/j.cattod.2014.06.040</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cattod.2014.06.040" target="_blank" >10.1016/j.cattod.2014.06.040</a>

Result language
angličtina
Original language name
Catalytic behavior of metal-organic frameworks and zeolites: Rationalization and comparative analysis
Original language description
The catalytic performance of selected MOFs (Cu-3(BTC)(2) and MIL-100(Fe)) and zeolites (BEA and USY) have been investigated in a set of acid-catalyzed reactions (Pechmann and Knoevenagel condensations, Friedel-Crafts acylation, Beckmann rearrangement, and Prins and annulation reactions). Characteristics determining the activity and selectivity of the catalysts (particularly their relation to the type and concentration of acid sites, the size of the channels, and structure of the active centers) were discussed in detail. The regular arrangement of active sites in MOFs was shown to provide their superior behavior in Pechmann and Knoevenagel condensation reaction, while higher porosity and concentration of mild Lewis acid centers allows the conversion ofbulky substrates to desired products over MOFs in Beckmann rearrangement, Friedel-Crafts acylation, and annulation reactions. Advantages and drawbacks of MOFs as catalysts were fairly compared with zeolites based on results obtained under
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA14-07101S" target="_blank" >GA14-07101S: Combined Experimental and Theoretical Investigation of Catalytic Properties of Metal Organic Frameworks</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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