Fabrication of Hybrid Organic-Inorganic Materials with Tunable Porosity for Catalytic Application
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00446861" target="_blank" >RIV/61388955:_____/15:00446861 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/cplu.201402346" target="_blank" >http://dx.doi.org/10.1002/cplu.201402346</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cplu.201402346" target="_blank" >10.1002/cplu.201402346</a>
Alternative languages
Result language
angličtina
Original language name
Fabrication of Hybrid Organic-Inorganic Materials with Tunable Porosity for Catalytic Application
Original language description
Novel layered organic-inorganic materials functionalized with amino groups have been synthesized by using a two-dimensional zeolitic precursor, IPC-1P, prepared by a top-down approach from zeolite UTL. The formation of porous materials containing silsesquioxane linkers covalently bonded to zeolite layers in the interlayer space was confirmed by a variety of characterization techniques (N(2)sorption, XRD, TEM). The textural properties and catalytic behavior of functionalized hybrid materials synthesizedby direct pillaring of IPC-1P or by grafting of (3-aminopropyl)silyl groups to the IPC-1P precursor preliminarily pillared with tetraethoxysilane (TEOS) were compared. The use of a mixture of aminosilsesquioxanes and TEOS for pillaring of IPC-1P led to the formation of functionalized materials, which are characterized by excellent textural properties (S-BET=154-435m(2)g(-1), V-total=0.336-0.630cm(3)g(-1)) and provide a 100% yield of target benzylidenemalononitrile in the Knoevenagel cond
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GP13-17593P" target="_blank" >GP13-17593P: Preparation of Novel Structure-Directing Agents for the Synthesis of Zeolites</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemPlusChem
ISSN
2192-6506
e-ISSN
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Volume of the periodical
80
Issue of the periodical within the volume
3
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
599-605
UT code for WoS article
000350471700021
EID of the result in the Scopus database
2-s2.0-84922773276