Product ion distributions for the reactions of NO+ with some N-containing and O-containing heterocyclic compounds obtained using SRI-TOF-MS

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00452355" target="_blank" >RIV/61388955:_____/15:00452355 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ijms.2015.06.003" target="_blank" >http://dx.doi.org/10.1016/j.ijms.2015.06.003</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ijms.2015.06.003" target="_blank" >10.1016/j.ijms.2015.06.003</a>

Result language
angličtina
Original language name
Product ion distributions for the reactions of NO+ with some N-containing and O-containing heterocyclic compounds obtained using SRI-TOF-MS
Original language description
Product ion distributions for the reactions of NO+ with nine O-containing and six N-containing heterocyclic compounds present in human volatilome have been determined under the conditions of a Selective Reagent Ionization Time of Flight Mass Spectrometer(SRI-TOF-MS) at E/N values in the drift tube reactor ranging from 90 to 130Td. This study was undertaken to provide the kinetics data by which these heterocyclic compounds could be analyzed in biogenic media using SRI-TOF-MS. The specific heterocyclic compounds are furan, 2-methylfuran, 3 -methylfuran, 2,5-dimethylfuran, 2-pentylfuran, 2,3-dihydrofuran, 1,3-dioxolane, 2-methyl-1,3-dioxolane, gamma-butyrolactone, pyrrole, 1-methylpyrrole, pyridine, 2,6-dimethylpyridine, pyrimidine, and 4-methylpyrimidine. Charge transfer was the dominant mechanism in the majority of these NO+ reactions generating the respective M+ parent cation, but in the pyridine, pyrimidine, and 4-methylpyrimidine reactions, stable NO+M adduct ions were the major pro
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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