Electrochemical and Theoretical Study of a New Series of Bicyclic Oxazaborines
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F16%3A00451456" target="_blank" >RIV/61388955:_____/16:00451456 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/16:39900572
Result on the web
<a href="http://dx.doi.org/10.1080/00032719.2015.1017761" target="_blank" >http://dx.doi.org/10.1080/00032719.2015.1017761</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/00032719.2015.1017761" target="_blank" >10.1080/00032719.2015.1017761</a>
Alternative languages
Result language
angličtina
Original language name
Electrochemical and Theoretical Study of a New Series of Bicyclic Oxazaborines
Original language description
Oxazaborines are stable precursors in the synthesis of triazaborine chromophores. Eight new oxazaborine derivatives bearing different donor and acceptor substituents were electrochemically investigated and the results were correlated with quantum calculations. The attention was focused on determination of the first oxidation and the first reduction potentials, their differences, and the relationships with the calculated highest occupied molecular orbital and lowest unoccupied molecular orbital energies. The electrochemical results, reflecting the locations of oxidation and reduction centers and intramolecular electron communication due to substituents, were correlated with the Hammett type sigma (para) constants using linear free energy relationships. Special cases are discussed and the reaction mechanisms are proposed.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Analytical Letters
ISSN
0003-2719
e-ISSN
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Volume of the periodical
49
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
178-187
UT code for WoS article
000363048900016
EID of the result in the Scopus database
2-s2.0-84944909873