Electrochemical Impedence Spectroscopy and Steady-State Voltammetry at the Micro- between Two Immiscible Electrolyte Solution
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F16%3A00459746" target="_blank" >RIV/61388955:_____/16:00459746 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Electrochemical Impedence Spectroscopy and Steady-State Voltammetry at the Micro- between Two Immiscible Electrolyte Solution
Original language description
The kinetic data of simple tetraethylammonium ion transfer across the water/1,2-DCE interface obtained by electrochemical impedance spectroscopy and steady-state voltammetry are compared. It is shown that the geometry of the microcapillary tip region is of critical importance to obtain reliable kinetic data. Quasi-reversible behavior of the ion transfer reaction, corresponding to an apparent standard rate constant of about 0.2 cm s-1, is observed with both experimental methods.n
Czech name
—
Czech description
—
Classification
Type
D - Article in proceedings
CEP classification
—
OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
<a href="/en/project/GA13-04630S" target="_blank" >GA13-04630S: Novel Methodology for the Determination of the Rate of Ion-Transfer Across Liquid/Liquid Interfaces (ITIES)</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
XXXVI. Moderní elektrochemické metody. Sborník přednášek
ISBN
978-80-905221-4-5
ISSN
—
e-ISSN
—
Number of pages
5
Pages from-to
191-195
Publisher name
Best servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 23, 2016
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000389898200044