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Fermionic Orbital Optimization in Tensor Network States

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F16%3A00465777" target="_blank" >RIV/61388955:_____/16:00465777 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1103/physrevlett.117.210402" target="_blank" >http://dx.doi.org/10.1103/physrevlett.117.210402</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1103/physrevlett.117.210402" target="_blank" >10.1103/physrevlett.117.210402</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Fermionic Orbital Optimization in Tensor Network States

  • Original language description

    Tensor network states and specifically matrix-product states have proven to be a powerful tool for simulating ground states of strongly correlated spin models. Recently, they have also been applied to interacting fermionic problems, specifically in the context of quantum chemistry. A new freedom arising in such nonlocal fermionic systems is the choice of orbitals, it being far from clear what choice of fermionic orbitals to make. In this Letter, we propose a way to overcome this challenge. We suggest a method intertwining the optimization over matrix product states with suitable fermionic Gaussian mode transformations. The described algorithm generalizes basis changes in the spirit of the Hartree-Fock method to matrix-product states, and provides a black box tool for basis optimization in tensor network methods.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA16-12052S" target="_blank" >GA16-12052S: DMRG-based externally corrected multireference coupled cluster methods</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Review Letters

  • ISSN

    0031-9007

  • e-ISSN

  • Volume of the periodical

    117

  • Issue of the periodical within the volume

    21

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000388284000001

  • EID of the result in the Scopus database

    2-s2.0-84995948251