In situ solid-state NMR and XRD studies of the ADOR process and the unusual structure of zeolite IPC-6

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00474117" target="_blank" >RIV/61388955:_____/17:00474117 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/17:10368241
Result on the web
<a href="http://dx.doi.org/10.1038/nchem.2761" target="_blank" >http://dx.doi.org/10.1038/nchem.2761</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1038/nchem.2761" target="_blank" >10.1038/nchem.2761</a>

Result language
angličtina
Original language name
In situ solid-state NMR and XRD studies of the ADOR process and the unusual structure of zeolite IPC-6
Original language description
The assembly-disassembly-organization-reassembly (ADOR) mechanism is a recent method for preparing inorganic framework materials and, in particular, zeolites. This flexible approach has enabled the synthesis of isoreticular families of zeolites with unprecedented continuous control over porosity, and the design and preparation of materials that would have been difficult-or even impossible-to obtain using traditional hydrothermal techniques. Applying the ADOR process to a parent zeolite with the UTL framework topology, for example, has led to six previously unknown zeolites (named IPC-n, where n = 2, 4, 6, 7, 9 and 10). To realize the full potential of the ADOR method, however, a further understanding of the complex mechanism at play is needed. Here, we probe the disassembly, organization and reassembly steps of the ADOR process through a combination of in situ solid-state NMR spectroscopy and powder X-ray diffraction experiments. We further use the insight gained to explain the formation of the unusual structure of zeolite IPC-6.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
<a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)