Interaction of the cesium cation with meso-octamethylcalix[4]pyrrole: Experimental and theoretical study

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00482760" target="_blank" >RIV/61388955:_____/17:00482760 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/17:74567 RIV/60461373:22310/17:43903845 RIV/60461373:22340/17:43903845
Result on the web
<a href="http://dx.doi.org/10.1016/j.cplett.2016.12.044" target="_blank" >http://dx.doi.org/10.1016/j.cplett.2016.12.044</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cplett.2016.12.044" target="_blank" >10.1016/j.cplett.2016.12.044</a>

Result language
angličtina
Original language name
Interaction of the cesium cation with meso-octamethylcalix[4]pyrrole: Experimental and theoretical study
Original language description
By using electrospray ionization mass spectrometry (ESI-MS), it was proven experimentally that the univalent cesium cation (Cs+) forms with meso-octamethylcalix[4]pyrrole (abbrev. 1) the cationic complex species 1.Cs+. Further, applying quantum chemical DFT calculations, four different conformations of the resulting complex 1.Cs+ were derived. It means that under the present experimental conditions, this ligand 1 can be considered as a macrocyclic receptor for the cesium cation.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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