Metal carbonyl complexes of potentially ambidentate 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole acceptors
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00506623" target="_blank" >RIV/61388955:_____/17:00506623 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0297834" target="_blank" >http://hdl.handle.net/11104/0297834</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1515/znb-2017-0100" target="_blank" >10.1515/znb-2017-0100</a>
Alternative languages
Result language
angličtina
Original language name
Metal carbonyl complexes of potentially ambidentate 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole acceptors
Original language description
The compounds [W(CO)(5)(btd)], [W(CO)(5)(bsd] and [Re(CO)(3)(bpy)(bsd)](BF4), btd = 2,1,3-benzothiadiazole and bsd = 2,1,3-benzoselenadiazole were isolated and characterized experimentally (crystal structure, spectroscopy, spectroelectrochemistry) and by density functional theory calculations. The results confirm single N-coordination in all cases, binding to Se was calculated to be less favorable. Studies of one-electron reduced forms indicate that the N-coordination is maintained during electron transfer.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift fur Naturforschung. Section B: a Journal of Chemical Sciences
ISSN
0932-0776
e-ISSN
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Volume of the periodical
72
Issue of the periodical within the volume
11
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
839-846
UT code for WoS article
000414628900010
EID of the result in the Scopus database
2-s2.0-85040576744