All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00490695" target="_blank" >RIV/61388955:_____/18:00490695 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1002/cctc.201800413" target="_blank" >http://dx.doi.org/10.1002/cctc.201800413</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/cctc.201800413" target="_blank" >10.1002/cctc.201800413</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface

  • Original language description

    Metallosilicate catalysts with tetrahedrally coordinated transition metals are attractive because of their high selectivity in the oxidation of hydrocarbons. Here, we report highly active titanosilicate catalysts featuring an isolated titanium species with a uniform tetrahedral coordination state, unusually high surface density, and high accessibility of the Ti active sites. The layered titanosilicate prepared by grafting of TiIVacetylacetonate onto the surfaces of the crystalline layered silicate, HUS-7, showed excellent catalytic performance in the epoxidation of cyclohexene with tert-butyl hydroperoxide as an oxidant (turnover frequency of 230h-1and reaction rate of 314mmolg-1h-1).

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    <a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ChemCatChem

  • ISSN

    1867-3880

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    5

  • Pages from-to

    2536-2540

  • UT code for WoS article

    000436933700003

  • EID of the result in the Scopus database

    2-s2.0-85046532144