Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00490695" target="_blank" >RIV/61388955:_____/18:00490695 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/cctc.201800413" target="_blank" >http://dx.doi.org/10.1002/cctc.201800413</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cctc.201800413" target="_blank" >10.1002/cctc.201800413</a>
Alternative languages
Result language
angličtina
Original language name
Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface
Original language description
Metallosilicate catalysts with tetrahedrally coordinated transition metals are attractive because of their high selectivity in the oxidation of hydrocarbons. Here, we report highly active titanosilicate catalysts featuring an isolated titanium species with a uniform tetrahedral coordination state, unusually high surface density, and high accessibility of the Ti active sites. The layered titanosilicate prepared by grafting of TiIVacetylacetonate onto the surfaces of the crystalline layered silicate, HUS-7, showed excellent catalytic performance in the epoxidation of cyclohexene with tert-butyl hydroperoxide as an oxidant (turnover frequency of 230h-1and reaction rate of 314mmolg-1h-1).
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GBP106%2F12%2FG015" target="_blank" >GBP106/12/G015: Intelligent design of nanoporous adsorbents and catalysts</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemCatChem
ISSN
1867-3880
e-ISSN
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Volume of the periodical
10
Issue of the periodical within the volume
12
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
2536-2540
UT code for WoS article
000436933700003
EID of the result in the Scopus database
2-s2.0-85046532144