On the mechanism of high-temperature N 2 O decomposition over Fe-FER in the presence of NOn

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00505954" target="_blank" >RIV/61388955:_____/18:00505954 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0297275" target="_blank" >http://hdl.handle.net/11104/0297275</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.catcom.2018.05.001" target="_blank" >10.1016/j.catcom.2018.05.001</a>

Result language
angličtina
Original language name
On the mechanism of high-temperature N 2 O decomposition over Fe-FER in the presence of NOn
Original language description
The role of NO in the N2O decomposition under conditions relevant to its formation by NH3 oxidation during nitric acid production over iron-containing ferrierite (Fe-FER) catalyst was investigated. In particular, the relative productions of O2 and NO2 during the high-temperature decomposition of N2O over Fe-FER as the result of the direct recombination of adsorbed atomic oxygen (Oat) and of NO oxidation steps, respectively, were evaluated. These results proved the enhanced role of the direct Oat recombination step at higher temperatures but surprisingly also indicated persistent and substantial elimination of N2O due to NO oxidation during the formation of NO2 at T ≥ 800 °C.nn
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)