Dissociative electron attachment to HNO3 and its hydrates: energy-selective electron-induced chemistry
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F19%3A00504200" target="_blank" >RIV/61388955:_____/19:00504200 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0295880" target="_blank" >http://hdl.handle.net/11104/0295880</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C9CP00990F" target="_blank" >10.1039/C9CP00990F</a>
Alternative languages
Result language
angličtina
Original language name
Dissociative electron attachment to HNO3 and its hydrates: energy-selective electron-induced chemistry
Original language description
We probe the negative ion production upon the interaction of free electrons with gas-phase HNO3 and its mixed clusters with water. The electron-induced chemistry changes strongly with clustering, exhibiting significant electron energy dependence. For HNO3 hydrates, we identified three involved energy ranges with different behavior: low energies up to about 3.5 eV, an intermediate energy range around 6 eV, and a high energy range, approximately above 9 eV. The major difference is the degree to which the major gas-phase product, NO2−, is converted to NO3−. The latter is the dominant stratospheric anion. Its appearance due to the electron interaction with mixed HNO3/water ice particles thus strongly depends on the electron energy. We discuss the elementary processes and reaction pathways behind the anion conversion.n
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physical Chemistry Chemical Physics
ISSN
1463-9076
e-ISSN
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Volume of the periodical
21
Issue of the periodical within the volume
APR 2019
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
8691-8697
UT code for WoS article
000474599300005
EID of the result in the Scopus database
2-s2.0-85065174694