(Spectro)electrochemical and Electrocatalytic Investigation of 1,1 '-Dithiolatoferrocene-Hexacarbonyldiiron

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F19%3A00505699" target="_blank" >RIV/61388955:_____/19:00505699 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0297111" target="_blank" >http://hdl.handle.net/11104/0297111</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.8b02971" target="_blank" >10.1021/acs.inorgchem.8b02971</a>

Result language
angličtina
Original language name
(Spectro)electrochemical and Electrocatalytic Investigation of 1,1 '-Dithiolatoferrocene-Hexacarbonyldiiron
Original language description
Hexacarbonyldiiron bridged by a 1,1'-dithiolatoferrocene, [Fe(C5H4S)(2){Fe(CO)(3)}(2)] (1), was synthesized, and the electrochemistry showed reversible oxidation at the Fe(C5H4S)(2) site and quasi-reversible reduction at the hexacarbonyldiiron site. Spectroelectro-chemical techniques showed reduction-induced ligand isomerization, where the thiolate ligand went from bridging to terminal and one carbon monoxide ligand moved to a quasi-bridging position. This mechanism was further supported by cyclic voltammetry simulation and density functional theory calculations. Complex 1 showed electrocatalytic activity toward hydrogen-evolving reaction.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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