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Facile construction & modeling of a highly active thiacalixphenyl[4]arene-protected nano-palladium catalyst for various C-C cross-coupling reactions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F19%3A00508039" target="_blank" >RIV/61388955:_____/19:00508039 - isvavai.cz</a>

  • Result on the web

    <a href="http://hdl.handle.net/11104/0298993" target="_blank" >http://hdl.handle.net/11104/0298993</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c8nj05866k" target="_blank" >10.1039/c8nj05866k</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Facile construction & modeling of a highly active thiacalixphenyl[4]arene-protected nano-palladium catalyst for various C-C cross-coupling reactions

  • Original language description

    The design and creation of thiacalixphenyl[4]arene tetraacetohydrazide (TPTAH) has been utilized for the construction of palladium nanoparticles (PdNps). The molecular modelling studies give an insight into the surface properties of TPTAH capped PdNps. The plausible reduction mechanism of Pd(ii) to Pd(0) is due to the presence of hydrazide group on the periphery. The charge transfer for this reduction was initiated by the carbonyl group and N-atom. TPTAH behaves as a reducing and stabilizing agent for the formation of catalytically active TPTAH-PdNps that were characterized by UV-Vis spectroscopy, selected area electron diffraction (SAED), transmission electron microscopy (TEM), and powder X-ray diffraction. The TPTAH-PdNps with size 4 ± 2 nm were found to be catalytically active for C-C cross-coupling reactions such as the Suzuki-Miyaura, Heck, and Stille reactions. TPTAH-PdNps are superior to the conventional Pd catalyst in terms of yield, catalyst loading, reaction time, and recyclability.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Result continuities

  • Project

    <a href="/en/project/GA17-18108S" target="_blank" >GA17-18108S: Novel electrochemically active thiacalix[4]arenes and their oxidized analogues as ligands and receptors</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    New Journal of Chemistry

  • ISSN

    1144-0546

  • e-ISSN

  • Volume of the periodical

    43

  • Issue of the periodical within the volume

    14

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    12

  • Pages from-to

    5611-5622

  • UT code for WoS article

    000464280500037

  • EID of the result in the Scopus database

    2-s2.0-85063689590