Facile construction & modeling of a highly active thiacalixphenyl[4]arene-protected nano-palladium catalyst for various C-C cross-coupling reactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F19%3A00508039" target="_blank" >RIV/61388955:_____/19:00508039 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0298993" target="_blank" >http://hdl.handle.net/11104/0298993</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8nj05866k" target="_blank" >10.1039/c8nj05866k</a>
Alternative languages
Result language
angličtina
Original language name
Facile construction & modeling of a highly active thiacalixphenyl[4]arene-protected nano-palladium catalyst for various C-C cross-coupling reactions
Original language description
The design and creation of thiacalixphenyl[4]arene tetraacetohydrazide (TPTAH) has been utilized for the construction of palladium nanoparticles (PdNps). The molecular modelling studies give an insight into the surface properties of TPTAH capped PdNps. The plausible reduction mechanism of Pd(ii) to Pd(0) is due to the presence of hydrazide group on the periphery. The charge transfer for this reduction was initiated by the carbonyl group and N-atom. TPTAH behaves as a reducing and stabilizing agent for the formation of catalytically active TPTAH-PdNps that were characterized by UV-Vis spectroscopy, selected area electron diffraction (SAED), transmission electron microscopy (TEM), and powder X-ray diffraction. The TPTAH-PdNps with size 4 ± 2 nm were found to be catalytically active for C-C cross-coupling reactions such as the Suzuki-Miyaura, Heck, and Stille reactions. TPTAH-PdNps are superior to the conventional Pd catalyst in terms of yield, catalyst loading, reaction time, and recyclability.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
<a href="/en/project/GA17-18108S" target="_blank" >GA17-18108S: Novel electrochemically active thiacalix[4]arenes and their oxidized analogues as ligands and receptors</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
New Journal of Chemistry
ISSN
1144-0546
e-ISSN
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Volume of the periodical
43
Issue of the periodical within the volume
14
Country of publishing house
GB - UNITED KINGDOM
Number of pages
12
Pages from-to
5611-5622
UT code for WoS article
000464280500037
EID of the result in the Scopus database
2-s2.0-85063689590