Preparation and redox properties of fluorinated 1,3-diphenylisobenzofurans
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F19%3A00508220" target="_blank" >RIV/61388955:_____/19:00508220 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/19:00508768
Result on the web
<a href="http://hdl.handle.net/11104/0299192" target="_blank" >http://hdl.handle.net/11104/0299192</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2019.134659" target="_blank" >10.1016/j.electacta.2019.134659</a>
Alternative languages
Result language
angličtina
Original language name
Preparation and redox properties of fluorinated 1,3-diphenylisobenzofurans
Original language description
Eleven fluorinated 1,3-diphenylisobenzofurans, materials that are promising to perform efficient singlet fission, have been synthesized and their electrochemical reduction and oxidation in non-aqueous dimethylformamide examined. The redox properties are not changed continuously with increasing number of fluorine substituents but there are some qualitative turns in behavior for specific types of substitution revealing a discontinuity requiring deeper investigation. The DFT calculations confirm the trends observed experimentally by correlation of experimental and calculated data. The differences between the geometries of the neutral species and their radical ions were computed and rationalized.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
<a href="/en/project/GA19-22806S" target="_blank" >GA19-22806S: Singlet Fission: Redox and Photophysics of Captodative Biradicaloids</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrochimica acta
ISSN
0013-4686
e-ISSN
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Volume of the periodical
321
Issue of the periodical within the volume
OCT 2019
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
134659
UT code for WoS article
000485837700023
EID of the result in the Scopus database
2-s2.0-85070671765