Dynamic covalent conjugated polymer epitaxy on graphene

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F19%3A00510535" target="_blank" >RIV/61388955:_____/19:00510535 - isvavai.cz</a>

Alternative codes found

RIV/00216208:11320/19:10406558

Result on the web

<a href="http://hdl.handle.net/11104/0300988" target="_blank" >http://hdl.handle.net/11104/0300988</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c9tc03155c" target="_blank" >10.1039/c9tc03155c</a>

Result language

angličtina

Original language name

Dynamic covalent conjugated polymer epitaxy on graphene

Original language description

Hybrid heterostructures formed from ordered molecular layers on two-dimensional materials can have unique properties differing from those of their bulk phases. By employing principles of dynamic covalent chemistry, we have synthesized a series of novel conjugated polyimines that form epitaxial ordered monolayers on graphene. The interplay between molecular physisorption and dynamic polymerization at the solid-liquid interface drives the formation of longer chains at the surface with dramatically higher rates than in solution. The physico-chemical properties of such assemblies at different length scales on graphene were investigated by a combination of experimental techniques. ´Covalent dynamic epitaxy´ was also found to modulate the properties of both substrate and dynamers such as doping and photoluminescence, respectively.

Czech name

—

Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10403 - Physical chemistry

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Materials Chemistry C

ISSN

2050-7526

e-ISSN

—

Volume of the periodical

7

Issue of the periodical within the volume

39

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

12240-12247

UT code for WoS article

000490152800019

EID of the result in the Scopus database

2-s2.0-85073393093