Mode-Specific Vibrational Autodetachment Following Excitation of Electronic Resonances by Electrons and Photons

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F20%3A00524778" target="_blank" >RIV/61388955:_____/20:00524778 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0309070" target="_blank" >http://hdl.handle.net/11104/0309070</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1103/PhysRevLett.124.203401" target="_blank" >10.1103/PhysRevLett.124.203401</a>

Result language
angličtina
Original language name
Mode-Specific Vibrational Autodetachment Following Excitation of Electronic Resonances by Electrons and Photons
Original language description
Electronic resonances commonly decay via internal conversion to vibrationally hot anions and subsequent statistical electron emission. We observed vibrational structure in such an emission from the nitrobenzene anion, in both the 2D electron energy loss and 2D photoelectron spectroscopy of the neutral and anion, respectively. The emission peaks could be correlated with calculated nonadiabatic coupling elements for vibrational modes to the electronic continuum from a nonvalence dipole-bound state. This autodetachment mechanism via a dipole-bound state is likely to be a common feature in both electron and photoelectron spectroscopies.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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