Electrochemical study of the anomalous salt extraction from water to a polar organic solvent

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F20%3A00533532" target="_blank" >RIV/61388955:_____/20:00533532 - isvavai.cz</a>

Result on the web

<a href="http://hdl.handle.net/11104/0311905" target="_blank" >http://hdl.handle.net/11104/0311905</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10008-020-04656-5" target="_blank" >10.1007/s10008-020-04656-5</a>

Result language

angličtina

Original language name

Electrochemical study of the anomalous salt extraction from water to a polar organic solvent

Original language description

Recently, we have reported an unusual phenomenon occurring at the polarized interface between two immiscible electrolyte solutions (ITIES), which is characterized by the anomalous salt extraction seemingly violating the classical partition law [1]. The preliminary results indicated that this extraction is probably driven by the formation of the hydrated salt clusters in the organic solvent phase [1]. Accumulation of water clusters may finally result in the formation of a water-in-oil emulsion [2]. Spontaneous emulsification at liquid/liquid boundaries can be of the great practical significance for separation, pharmaceutical, chemical, foods, and cosmetic applications [3]. Related studies have dealt with the structure and stability of water clusters [4, 5], and the hydration of ions [6, 7], in the hydrophobic polar solvent like nitrobenzene (NB) or 1,2-dichloroethane (DCE)...

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project

<a href="/en/project/GA20-01589S" target="_blank" >GA20-01589S: New strategies for improving sensing properties of novel electrode materials via their surface pretreatment or modification</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2020

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Solid State Electrochemistry

ISSN

1432-8488

e-ISSN

—

Volume of the periodical

24

Issue of the periodical within the volume

9

Country of publishing house

DE - GERMANY

Number of pages

2

Pages from-to

2173-2174

UT code for WoS article

000539527800004

EID of the result in the Scopus database

2-s2.0-85086336395