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Atomic Absorption Spectroscopy Reveals Anomalous Transfer of Heavy Metal across a Water/1,2-DCE Interface

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F21%3A00549119" target="_blank" >RIV/61388955:_____/21:00549119 - isvavai.cz</a>

  • Result on the web

    <a href="http://hdl.handle.net/11104/0325133" target="_blank" >http://hdl.handle.net/11104/0325133</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.4152/pea.2021390603" target="_blank" >10.4152/pea.2021390603</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Atomic Absorption Spectroscopy Reveals Anomalous Transfer of Heavy Metal across a Water/1,2-DCE Interface

  • Original language description

    Atomic absorption spectroscopy (AAS) of samples taken from the organic phase of a water/1,2-dichloroethane (1,2-DCE) interfacial electrochemical cell, rendered non-polarizable by the tetraphenylarsonium common-ion, revealed significant transfer of heavy metal from the aqueous phase. Heavy metal concentration found within 1,2-DCE cannot be explained via ion pair formation between the metallic species and the commonion, nor by ion pair formation between the metallic species and the hydrophobic anion of the organic phase. Results suggest that metal may have been anomalously transferred into 1,2-DCE within water-in-oil droplets formed by spontaneous emulsification of the interfacial region.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    <a href="/en/project/GA17-09980S" target="_blank" >GA17-09980S: Biomimetic electrochemistry of emulsion micro-droplets at the polarised interface between two immiscible electrolyte solutions</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Portugaliae Electrochimica Acta

  • ISSN

    0872-1904

  • e-ISSN

    0872-1904

  • Volume of the periodical

    39

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    PT - PORTUGAL

  • Number of pages

    6

  • Pages from-to

    415-420

  • UT code for WoS article

    000721144400003

  • EID of the result in the Scopus database

    2-s2.0-85122759061