Atomic Absorption Spectroscopy Reveals Anomalous Transfer of Heavy Metal across a Water/1,2-DCE Interface
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F21%3A00549119" target="_blank" >RIV/61388955:_____/21:00549119 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0325133" target="_blank" >http://hdl.handle.net/11104/0325133</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.4152/pea.2021390603" target="_blank" >10.4152/pea.2021390603</a>
Alternative languages
Result language
angličtina
Original language name
Atomic Absorption Spectroscopy Reveals Anomalous Transfer of Heavy Metal across a Water/1,2-DCE Interface
Original language description
Atomic absorption spectroscopy (AAS) of samples taken from the organic phase of a water/1,2-dichloroethane (1,2-DCE) interfacial electrochemical cell, rendered non-polarizable by the tetraphenylarsonium common-ion, revealed significant transfer of heavy metal from the aqueous phase. Heavy metal concentration found within 1,2-DCE cannot be explained via ion pair formation between the metallic species and the commonion, nor by ion pair formation between the metallic species and the hydrophobic anion of the organic phase. Results suggest that metal may have been anomalously transferred into 1,2-DCE within water-in-oil droplets formed by spontaneous emulsification of the interfacial region.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA17-09980S" target="_blank" >GA17-09980S: Biomimetic electrochemistry of emulsion micro-droplets at the polarised interface between two immiscible electrolyte solutions</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Portugaliae Electrochimica Acta
ISSN
0872-1904
e-ISSN
0872-1904
Volume of the periodical
39
Issue of the periodical within the volume
6
Country of publishing house
PT - PORTUGAL
Number of pages
6
Pages from-to
415-420
UT code for WoS article
000721144400003
EID of the result in the Scopus database
2-s2.0-85122759061